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The role of neutral donor ligands in the isoselective ring-opening polymerization of rac-β-butyrolactone

Isoenriched poly-3-hydroxybutyrate (P3HB) is a biodegradable material with properties similar to isotactic polypropylene, yet efficient routes to this material are lacking after 50+ years of extensive efforts in catalyst design. In this contribution, a novel lanthanum aminobisphenolate catalyst (1-L...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Dong, Xiang, Robinson, Jerome R.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163396/
https://ncbi.nlm.nih.gov/pubmed/34123089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03507f
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