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Phosphasalen Indium Complexes Showing High Rates and Isoselectivities in rac‐Lactide Polymerizations

Polylactide (PLA) is the leading bioderived polymer produced commercially by the metal‐catalyzed ring‐opening polymerization of lactide. Control over tacticity to produce stereoblock PLA, from rac‐lactide improves thermal properties but is an outstanding challenge. Here, phosphasalen indium catalyst...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Myers, Dominic, White, Andrew J. P., Forsyth, Craig M., Bown, Mark, Williams, Charlotte K.
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5434947/
https://ncbi.nlm.nih.gov/pubmed/28378455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701745
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