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Fe-mediated HER vs N(2)RR: Exploring Factors that Contribute to Selectivity in P(3)(E)Fe(N(2)) (E = B, Si, C) Catalyst Model Systems
Mitigation of the hydrogen evolution reaction (HER) is a key challenge in selective small molecule reduction catalysis. This is especially true of catalytic nitrogen (N(2)) and carbon dioxide (CO(2)) reduction reactions (N(2)RR and CO(2)RR, respectively) using H(+)/e(−) currency. Here we explore, vi...
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| Veröffentlicht in: | ACS Catal |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6289286/ https://ncbi.nlm.nih.gov/pubmed/30555733 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03068 |
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