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Fe-mediated HER vs N(2)RR: Exploring Factors that Contribute to Selectivity in P(3)(E)Fe(N(2)) (E = B, Si, C) Catalyst Model Systems

Mitigation of the hydrogen evolution reaction (HER) is a key challenge in selective small molecule reduction catalysis. This is especially true of catalytic nitrogen (N(2)) and carbon dioxide (CO(2)) reduction reactions (N(2)RR and CO(2)RR, respectively) using H(+)/e(−) currency. Here we explore, vi...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Matson, Benjamin D., Peters, Jonas C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6289286/
https://ncbi.nlm.nih.gov/pubmed/30555733
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03068
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