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Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls
β‐Diketiminato (BDI) calcium alkyl derivatives undergo hydrogenolysis with H(2) to regenerate [(BDI)CaH](2), allowing the catalytic hydrogenation of a wide range of 1‐alkenes and norbornene under very mild conditions (2 bar H(2), 298 K). The reactions are deduced to take place with the retention of...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6282996/ https://ncbi.nlm.nih.gov/pubmed/30289589 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809833 |
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