Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls

β‐Diketiminato (BDI) calcium alkyl derivatives undergo hydrogenolysis with H(2) to regenerate [(BDI)CaH](2), allowing the catalytic hydrogenation of a wide range of 1‐alkenes and norbornene under very mild conditions (2 bar H(2), 298 K). The reactions are deduced to take place with the retention of...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Wilson, Andrew S. S., Dinoi, Chiara, Hill, Michael S., Mahon, Mary F., Maron, Laurent
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2018
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6282996/
https://ncbi.nlm.nih.gov/pubmed/30289589
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809833
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