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Synthesis of Chiral, Enantiopure Allylic Amines by the Julia Olefination of α-Amino Esters
The four-step conversion of a series of N-Boc-protected l-amino acid methyl esters into enantiopure N-Boc allylamines by a modified Julia olefination is described. Key steps include the reaction of a lithiated phenylalkylsulfone with amino esters, giving chiral β-ketosulfones, and the reductive elim...
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| 出版年: | Molecules |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
MDPI
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6273449/ https://ncbi.nlm.nih.gov/pubmed/27338326 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21060805 |
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