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Catalytic Asymmetric Synthesis of Chiral Allylic Esters
A broadly useful catalytic enantioselective synthesis of branched allylic esters from prochiral (Z)-2-alkene-1-ols has been developed. The starting allylic alcohol is converted to its trichloroacetimidate intermediate by reaction with trichloroacetonitrile, either in situ or in a separate step, and...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2005
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2966826/ https://ncbi.nlm.nih.gov/pubmed/15740118 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0425583 |
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