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Catalytic Asymmetric Synthesis of Chiral Allylic Esters

A broadly useful catalytic enantioselective synthesis of branched allylic esters from prochiral (Z)-2-alkene-1-ols has been developed. The starting allylic alcohol is converted to its trichloroacetimidate intermediate by reaction with trichloroacetonitrile, either in situ or in a separate step, and...

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Bibliografske podrobnosti
Main Authors: Cannon, Jeffrey S., Kirsch, Stefan F., Overman, Larry E.
Format: Artigo
Jezik:Inglês
Izdano: 2005
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2966826/
https://ncbi.nlm.nih.gov/pubmed/15740118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0425583
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