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Seven-Membered Rings through Metal-Free Rearrangement Mediated by Hypervalent Iodine
A versatile and metal-free approach for the synthesis of carbocycles and of heterocycles bearing seven- and eight-membered rings is described. The strategy is based on ring expansion of 1-vinylcycloalkanols (or the corresponding silyl or methyl ether) mediated by the hypervalent iodine reagent HTIB...
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| Publié dans: | Molecules |
|---|---|
| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6272645/ https://ncbi.nlm.nih.gov/pubmed/25599151 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules20011475 |
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