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Trans-Selective Rhodium Catalysed Conjugate Addition of Organoboron Reagents to Dihydropyranones

The selective synthesis of 2,6-trans-tetrahydropyran derivatives employing the rhodium catalysed addition of organoboron reagents to dihydropyranone templates, derived from a zinc-catalysed hetero-Diels-Alder reaction, is reported. The addition of both arylboronic acids and potassium alkenyltrifluor...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Edwards, Hannah J., Goggins, Sean, Frost, Christopher G.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6272642/
https://ncbi.nlm.nih.gov/pubmed/25856064
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules20046153
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