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The Application of Transient-State Kinetic Isotope Effects to the Resolution of Mechanisms of Enzyme-Catalyzed Reactions

Much of our understanding of the mechanisms of enzyme-catalyzed reactions is based on steady-state kinetic studies. Experimentally, this approach depends solely on the measurement of rates of free product appearance (d[P]/dt), a mechanistically and mathematically complex entity. Despite the ambiguit...

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Detalles Bibliográficos
Publicado en:Molecules
Autor principal: Fisher, Harvey F.
Formato: Artigo
Lenguaje:Inglês
Publicado: MDPI 2013
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6269668/
https://ncbi.nlm.nih.gov/pubmed/23857126
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules18078230
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