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Hydroamination versus Allylic Amination in Iridium Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity
In the presence of a neutral dppf-modified iridium catalyst and Cs(2)CO(3), linear allylic acetates react with primary amines to form products of hydroamination with complete 1,3-regioselectivity. The collective data, including deuterium labeling studies, corroborate a catalytic mechanism involving...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6264884/ https://ncbi.nlm.nih.gov/pubmed/29989803 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05683 |
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