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Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La(2)@I(h)-C(80). NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The ele...

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發表在:Molecules
Main Authors: Yamada, Michio, Someya, Chika I., Nakahodo, Tsukasa, Maeda, Yutaka, Tsuchiya, Takahiro, Akasaka, Takeshi
格式: Artigo
語言:Inglês
出版: MDPI 2011
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264206/
https://ncbi.nlm.nih.gov/pubmed/22083236
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16119495
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