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Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes

The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La(2)@C(80) or La@C(82), afforded the novel derivatives of endohedral metallofullerenes (3a,b, 4a,b and 5b). Molecula...

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Detalhes bibliográficos
Main Authors: Takano, Yuta, Nagashima, Yuki, Herranz, M Ángeles, Martín, Nazario, Akasaka, Takeshi
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3999875/
https://ncbi.nlm.nih.gov/pubmed/24778724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.65
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