Photoreactions of Endohedral Metallofullerene with Siliranes: Electronic Properties of Carbosilylated Lu(3)N@I(h)-C(80) †

Photochemical carbosilylation of Lu(3)N@I(h)-C(80) was performed using siliranes (silacyclopropanes) to afford the corresponding [5,6]- and [6,6]-adducts. Electrochemical studies indicated that the redox potentials of the carbosilylated derivatives were shifted cathodically in comparison with those...

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Veröffentlicht in:Molecules
Hauptverfasser: Kako, Masahiro, Minami, Kazuya, Kuroiwa, Taiki, Fukazawa, Shinpei, Arikawa, Yuki, Yamada, Michio, Maeda, Yutaka, Li, Qiao-Zhi, Nagase, Shigeru, Akasaka, Takeshi
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI 2017
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6154294/
https://ncbi.nlm.nih.gov/pubmed/28531116
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22050850
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