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Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones

A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalys...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Matsukawa, Satoru, Sekine, Izumi, Iitsuka, Ayumi
Formato: Artigo
Idioma:Inglês
Publicado em: Molecular Diversity Preservation International 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6254716/
https://ncbi.nlm.nih.gov/pubmed/19783929
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules14093353
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