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A Cooperative Ternary Catalysis System for Asymmetric Lactonizations of α-Ketoesters

A general and enantioselective N-heterocyclic carbene (NHC)-catalyzed lactonization of simple enals and α-ketoesters has been discovered using a new ternary cooperative catalytic system. The highly selective annulation was achieved by using a combination of a chiral NHC, a hydrogen-bond donor, and a...

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Detalhes bibliográficos
Publicado no:Adv Synth Catal
Main Authors: Murauski, Kathleen J. R., Walden, Daniel M., Cheong, Paul Ha-Yeon, Scheidt, Karl A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6251415/
https://ncbi.nlm.nih.gov/pubmed/30473657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201701015
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