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Redox-triggered cascade dearomative cyclizations enabled by hexafluoroisopropanol
An unprecedented cascade dearomative cyclization through hydrogen-bonding-assisted hydride transfer is realized. The aggregate effect of HFIP enables the rapid buildup of polycyclic amines directly from phenols and o-aminobenzaldehydes via a cascade dearomatization/rearomatization/dearomatization se...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6240893/ https://ncbi.nlm.nih.gov/pubmed/30542574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03339k |
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