טוען...
Critical computational analysis illuminates the reductive-elimination mechanism that activates nitrogenase for N(2) reduction
Recent spectroscopic, kinetic, photophysical, and thermodynamic measurements show activation of nitrogenase for N(2) → 2NH(3) reduction involves the reductive elimination (re) of H(2) from two [Fe–H–Fe] bridging hydrides bound to the catalytic [7Fe–9S–Mo–C–homocitrate] FeMo-cofactor (FeMo-co). These...
שמור ב:
| הוצא לאור ב: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
National Academy of Sciences
2018
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6233137/ https://ncbi.nlm.nih.gov/pubmed/30355772 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1810211115 |
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