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CO(2) Reduction Catalyzed by Nitrogenase: Pathways to Formate, Carbon Monoxide, and Methane
The reduction of N(2) to NH(3) by Mo-dependent nitrogenase at its active-site metal cluster FeMo-cofactor utilizes reductive elimination (re) of Fe-bound hydrides with obligatory loss of H(2) to activate the enzyme for binding/reduction of N(2). Earlier work showed that wild type nitrogenase and a n...
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| Publicado en: | Inorg Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5068488/ https://ncbi.nlm.nih.gov/pubmed/27500789 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b00388 |
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