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RING-CLOSING METATHESIS STRATEGY TO UNSATURATED γ- AND δ-LACTONES: SYNTHESIS OF HYDROXYETHYLENE ISOSTERE FOR PROTEASE INHIBITORS

Ring-closing olefin metathesis of acrylates derived from allylic and homo allylic alcohols in the presence of the Grubbs’ catalyst (10–15 mol%) and titanium isopropoxide (0.3–3 equiv) provided ready access to α, β-unsaturated γ- and δ-lactones and an important dipeptide isostere intermediate....

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Foilsithe in:Tetrahedron Lett
Main Authors: Ghosh, Arun K., Cappiello, John, Shin, Dongwoo
Formáid: Artigo
Teanga:Inglês
Foilsithe: 1998
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6223311/
https://ncbi.nlm.nih.gov/pubmed/30422130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(98)00887-9
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