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A cyclopropenethione-phosphine ligation for rapid biomolecule labeling
Cyclopropenethiones are reported as new bioorthogonal reagents. These motifs react readily with substituted phosphines to provide thiocarbonyl adducts. In some cases, the ligations are >300-fold faster than analogous reactions with bioorthogonal cyclopropenones. Dialkyl cyclopropenethiones are al...
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| Publicado no: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6219755/ https://ncbi.nlm.nih.gov/pubmed/30207474 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02296 |
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