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Cyclopropeniminium ions exhibit unique reactivity profiles with bioorthogonal phosphines
We report a new ligation of cyclopropeniminium ions with bioorthogonal phosphines. Cyclopropeniminium scaffolds are sufficiently stable in biological media and, unlike related isomers, react with functionalized phosphines via formal 1,2-addition to a π-system. The ligation can be performed in aqueou...
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| Gepubliceerd in: | J Org Chem |
|---|---|
| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2019
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6758563/ https://ncbi.nlm.nih.gov/pubmed/31083911 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00518 |
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