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Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
Selective creation of quaternary carbon centers has been a long-standing challenge in synthetic chemistry. We report here the chromium-catalyzed, para-selective formation of arylated quaternary carbon centers by alkylative reactions of benzamide derivatives with tertiary alkylmagnesium bromides at r...
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Udgivet i: | Nat Commun |
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Main Authors: | , , , , |
Format: | Artigo |
Sprog: | Inglês |
Udgivet: |
Nature Publishing Group UK
2018
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Fag: | |
Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6219510/ https://ncbi.nlm.nih.gov/pubmed/30401829 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07069-1 |
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