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Endo and Exo Diels-Alder Adducts: Temperature-Tunable Building Blocks for Selective Chemical Functionalization
The development and application of a novel endo furan-protected maleimide building block is reported. The endo isomer undergoes deprotection at temperatures ~50 °C below the exo derivative. This enables a simple and powerful approach to quantitatively and selectively introduce functional maleimide g...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6205238/ https://ncbi.nlm.nih.gov/pubmed/29613783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01544 |
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