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Cation-π Interactions in the Benzylic Arylation of Toluenes with Bimetallic Catalysts
A method to directly arylate toluene derivatives with aryl bromides to generate diarylmethanes, which are important building blocks in drug discovery, is described. In this method, KN(SiMe(3))(2) in combination with a (NIXANTPHOS)Pd catalyst accomplished the deprotonative activation of toluene deriv...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6200331/ https://ncbi.nlm.nih.gov/pubmed/30185030 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05143 |
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