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NMR spectroscopy studies of electronic effects and equilibrium in the organogold-to-boron transmetalation reaction and studies towards its application to the alkoxyboration addition of boron–oxygen σ bonds to alkynes
Electronic effects in the transmetalation of an aryl group from gold to boron were investigated by NMR spectroscopy. The transmetalation reaction is more facile for increasingly electrophilic boron reagents and is in equilibrium under certain conditions. Observed tetracoordinate boronate compounds s...
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| Udgivet i: | Tetrahedron |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6195222/ https://ncbi.nlm.nih.gov/pubmed/30344348 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.04.019 |
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