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Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes

[Image: see text] For nearly 70 years, the addition of boron–X σ bonds to carbon–carbon multiple bonds has been employed in the preparation of organoboron reagents. However, the significantly higher strength of boron–oxygen bonds has thus far precluded their activation for addition, preventing a dir...

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Detalhes bibliográficos
Main Authors: Hirner, Joshua J., Faizi, Darius J., Blum, Suzanne A.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3986241/
https://ncbi.nlm.nih.gov/pubmed/24588331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja500463p
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