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H(2)O(2) Oxidation by Fe(III)–OOH Intermediates and Its Effect on Catalytic Efficiency
[Image: see text] The oxidation of the C–H and C=C bonds of hydrocarbons with H(2)O(2) catalyzed by non-heme iron complexes with pentadentate ligands is widely accepted as involving a reactive Fe(IV)=O species such as [(N4Py)Fe(IV)=O](2+) formed by homolytic cleavage of the O–O bond of an Fe(III)–OO...
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| Publicat a: | ACS Catal |
|---|---|
| Autors principals: | , , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical Society
2018
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| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6179451/ https://ncbi.nlm.nih.gov/pubmed/30319886 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b02326 |
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