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Chiral Aniline Synthesis via Stereospecific C(sp(3))–C(sp(2)) Coupling of Boronic Esters with Aryl Hydrazines
[Image: see text] An enantiospecific coupling between alkylboronic esters and lithiated aryl hydrazines is described. The reaction proceeds under transition-metal-free conditions and is promoted by acylation of a hydrazinyl arylboronate complex, which triggers a N–N bond cleavage with concomitant 1,...
Enregistré dans:
| Publié dans: | Org Lett |
|---|---|
| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
American
Chemical Society
2018
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| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6178205/ https://ncbi.nlm.nih.gov/pubmed/30221524 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02615 |
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