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Functionalized Cyclopentanes via Sc(III)-Catalyzed Intramolecular Enolate Alkylation
We report herein the intramolecular α-tert-alkylation of unsaturated β-ketoesters which gives rise to highly functionalized cyclopentanes. This strategy is characterized by its operational simplicity, mild reaction conditions and the use of scandium(III) triflate as a Lewis acid catalyst. Of interes...
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| Foilsithe in: | Tetrahedron |
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| Main Authors: | , , , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2018
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6152925/ https://ncbi.nlm.nih.gov/pubmed/30262933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.04.036 |
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