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Pd-Catalyzed Alkene Difunctionalization Reactions of Enolates for the Synthesis of Substituted Bicyclic Cyclopentanes.

Palladium-catalyzed alkene difunctionalization reactions between alkenes bearing tethered aryl or alkenyl triflates and enolate nucleophiles are described. The transformations form two C–C bonds, a ring, and up to two stereocenters, while producing substituted cyclopentane derivatives that contain a...

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Dettagli Bibliografici
Pubblicato in:Org Process Res Dev
Autori principali: Bornowski, Evan C., Hinds, Elsa M., White, Derick R., Nakamura, Yusuke, Wolfe, John P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7886259/
https://ncbi.nlm.nih.gov/pubmed/33597795
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.oprd.9b00248
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