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Synthesis of 2,5-Disubstituted Octahydroquinolin-4-ones via an Intramolecular Hetero Diels-Alder Reaction

A route for the preparation of 2,5-disubstituted octahydroquinolin-4-ones,  synthetic precursors of the decahydroquinoline-type toxins, is presented. The key steps are an asymmetric epoxidation and an intramolecular hetero Diels-Alder reaction between an activated diene and an imine. The presence of...

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Bibliografske podrobnosti
izdano v:Molecules
Main Authors: Ruiz, Juan M., Afonso, María M., Palenzuela, J. Antonio
Format: Artigo
Jezik:Inglês
Izdano: MDPI 2007
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6149372/
https://ncbi.nlm.nih.gov/pubmed/17846570
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/12020194
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