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Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles

Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO(4) or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives. The hetero-Diels–Alder reaction occurs in a chemo- and regioselec...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Mlostoń, Grzegorz, Grzelak, Paulina, Mikina, Maciej, Linden, Anthony, Heimgartner, Heinz
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4464410/
https://ncbi.nlm.nih.gov/pubmed/26124858
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.63
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