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Formally Copper(III)−Alkylperoxo Complexes as Models of Possible Intermediates in Monooxygenase Enzymes
Reaction of [NBu(4)][LCu(II)OH] with excess ROOH (R = cumyl or tBu) yielded [NBu(4)][LCu(II)OOR], the reversible one-electron oxidation of which generated novel species with [CuOOR](2+) cores (formally Cu(III)OOR), identified by spectroscopy and theory for the case R = cumyl. This species reacts wit...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6132249/ https://ncbi.nlm.nih.gov/pubmed/28722408 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05754 |
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