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Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethylsilane: a general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer
We show that cobalt bis(acetylacetonate) [Co(acac)(2)], tert-butyl hydroperoxide (TBHP), and triethylsilane (Et(3)SiH) constitute an inexpensive, general, and practical reagent combination to initiate a broad range of Markovnikov-selective alkene hydrofunctionalization reactions. These transformatio...
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| Pubblicato in: | Beilstein J Org Chem |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Beilstein-Institut
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6122341/ https://ncbi.nlm.nih.gov/pubmed/30202480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.201 |
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