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Mechanistic Insight into the Photoredox Catalysis of Anti-Markovnikov Alkene Hydrofunctionalization Reactions

[Image: see text] We describe our efforts to understand the key mechanistic aspects of the previously reported alkene hydrofunctionalization reactions using 9-mesityl-10-methylacridinium (Mes-Acr(+)) as a photoredox catalyst. Importantly, we are able to detect alkene cation radical intermediates, an...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Romero, Nathan A., Nicewicz, David A.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4277776/
https://ncbi.nlm.nih.gov/pubmed/25390821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506228u
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