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Achieving High Ortho Selectivity in Aniline C–H Borylations by Modifying Boron Substituents
High ortho selectivity for Ir-catalyzed C–H borylations (CHBs) of anilines results when B(2)eg(2) (eg = ethylene glycolate) is used as the borylating reagent in lieu of B(2)pin(2), which is known to give isomeric mixtures with anilines lacking a blocking group at the 4-position. With this modificati...
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| Publicado no: | ACS Catal |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6105271/ https://ncbi.nlm.nih.gov/pubmed/30147990 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b00641 |
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