Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis

[Image: see text] Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.

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Detalhes bibliográficos
Main Authors: Ghaffari, Behnaz, Preshlock, Sean M., Plattner, Donald L., Staples, Richard J., Maligres, Peter E., Krska, Shane W., Maleczka, Robert E., Smith, Milton R.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4210111/
https://ncbi.nlm.nih.gov/pubmed/25141136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506229s
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