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Complete Switch of Reaction Specificity of an Aldolase by Directed Evolution In Vitro: Synthesis of Generic Aliphatic Aldol Products

A structure‐guided engineering of fructose‐6‐phosphate aldolase was performed to expand its substrate promiscuity toward aliphatic nucleophiles, that is, unsubstituted alkanones and alkanals. A “smart” combinatorial library was created targeting residues D6, T26, and N28, which form a binding pocket...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Junker, Sebastian, Roldan, Raquel, Joosten, Henk‐Jan, Clapés, Pere, Fessner, Wolf‐Dieter
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2018
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6099348/
https://ncbi.nlm.nih.gov/pubmed/29882622
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804831
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