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Synthesis of Azolo[1,3,5]triazines via Rhodium(III)-Catalyzed Annulation of N-Azolo Imines and Dioxazolones

A wide range of azolo[1,3,5]triazines were obtained by Rh(III)-catalyzed annulation of N-azolo imines and dioxazolones. The reaction proceeds by the first catalytic C-H amidation of an imidoyl C-H bond followed by cyclodehydration. Good yields were obtained for N-azolo imines derived from aminoazole...

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Publicat a:J Org Chem
Autors principals: Hoang, Gia L., Halskov, Kim Søholm, Ellman, Jonathan A.
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6097942/
https://ncbi.nlm.nih.gov/pubmed/29947517
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b01249
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