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Fusing Triphenylphosphine with Tetraphenylborate: Introducing the 9-Phosphatriptycene-10-phenylborate (PTB) Anion

In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh(3)) and tetraphenylborate (BPh(4)(−)), the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time. This borato species has been fully characterized by a suite of spectroscopic methods, and in...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Drover, Marcus W., Nagata, Koichi, Peters, Jonas C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6095131/
https://ncbi.nlm.nih.gov/pubmed/29951661
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc04321c
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