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Expanding the allyl analogy: accessing η(3)-P,B,P diphosphinoborane complexes of group 10
Using the diphosphinoborane, (PPh(2))(2)BMes (Mes = 2,4,6-Me(3)C(6)H(3)), we report the first examples of η(3)-P,B,P-ligated complexes using Ni(0) and Pt(ii). Reaction of (PPh(2))(2)BMes with Ni(COD)(2) or Pt(COD)Me(2) (COD = 1,5-cyclooctadiene) results in gradual COD displacement to give [η(3)-P,B,...
Gardado en:
| Publicado en: | Dalton Trans |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2018
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6005356/ https://ncbi.nlm.nih.gov/pubmed/29441396 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt00058a |
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