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Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes and Their Diastereoisomeric Congeners using Asymmetric Hydrovinylation for Absolute Stereochemical Control
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products including di- and tri-terpenes and steroids. Installation of these centers has been a long-standing problem in org...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6082684/ https://ncbi.nlm.nih.gov/pubmed/30001133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03549 |
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