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Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes and Their Diastereoisomeric Congeners using Asymmetric Hydrovinylation for Absolute Stereochemical Control
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products including di- and tri-terpenes and steroids. Installation of these centers has been a long-standing problem in org...
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| Опубликовано в: : | J Am Chem Soc |
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| Главные авторы: | , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2018
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6082684/ https://ncbi.nlm.nih.gov/pubmed/30001133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03549 |
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