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Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins

In this report we highlight the significant potential of ethylene as a reagent for the introduction of a vinyl group with excellent stereoselectivity at three different stages in the synthesis of a broad class of natural products, best exemplified by syntheses of pseudopterosins. The late-stage appl...

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Autori principali: Mans, Daniel J., Cox, G. Adam, RajanBabu, T. V.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3087302/
https://ncbi.nlm.nih.gov/pubmed/21449569
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201321v
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