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Enantioselective synthesis of 2-oxazolidinones by ruthenium(ii)–NHC-catalysed asymmetric hydrogenation of 2-oxazolones

An efficient synthesis of optically active 4-substituted 2-oxazolidinones by the ruthenium(ii)–NHC-catalysed asymmetric hydrogenation of 2-oxazolones was developed. Excellent enantioselectivities (up to 96% ee) and yields (up to 99%) were obtained for a variety of substrates, bearing a range of func...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Li, Wei, Wollenburg, Marco, Glorius, Frank
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6063072/
https://ncbi.nlm.nih.gov/pubmed/30090313
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01869c
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