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Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes

Following the report on the successful use of SiNN pincer complexes of iridium as catalysts for dehydrogenative borylation of terminal alkynes (DHBTA) to alkynylboronates, this work examined a wide variety of related pincer ligands in the supporting role in DHBTA. The ligand selection included both...

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Publicado en:Chem Sci
Autores principales: Lee, Chun-I, DeMott, Jessica C., Pell, Christopher J., Christopher, Alyson, Zhou, Jia, Bhuvanesh, Nattamai, Ozerov, Oleg V.
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2015
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054099/
https://ncbi.nlm.nih.gov/pubmed/30090274
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02161h
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