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Selective acceleration of disfavored enolate addition reactions by anion–π interactions

In chemistry and biology, cation–π interactions contribute significantly to many important transformations. In sharp contrast, reactions accomplished with support from the complementary anion–π interactions are essentially unknown. In this report, we show that anion–π interactions can determine the...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Zhao, Yingjie, Benz, Sebastian, Sakai, Naomi, Matile, Stefan
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2015
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054047/
https://ncbi.nlm.nih.gov/pubmed/30090238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02563j
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