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Anion-π Enzymes

[Image: see text] In this report, we introduce artificial enzymes that operate with anion-π interactions, an interaction that is essentially new to nature. The possibility to stabilize anionic intermediates and transition states on an π-acidic surface has been recently demonstrated, using the additi...

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Vydáno v:ACS Cent Sci
Hlavní autoři: Cotelle, Yoann, Lebrun, Vincent, Sakai, Naomi, Ward, Thomas R., Matile, Stefan
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2016
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4919773/
https://ncbi.nlm.nih.gov/pubmed/27413782
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00097
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